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Dramatic Influence of Nitrogen Heterocycles on the Activity of Low-Valent Titanium Reagent: An Improved One-Pot Synthesis of Phenanthrenes

Publication Type : Journal Article

Publisher : Taylor & Francis,

Source : Synthetic communications, Taylor & Francis, Volume 25, Number 2, p.135–142 (1995)

Campus : Amritapuri

School : School of Biotechnology

Department : biotechnology

Year : 1995

Abstract : A novel low-valent titanium (LVT) induced one-pot synthesis of phenanthrenes (25–38% yield) from ortho-alkoxy aromatic aldehydes/ketones was reported by us earlier. Activity of LVT complex could be modulated rationally by using catalytic amount of pyridine. Use of this LVT-pyridine reagent system improved the yields of phenanthrenes (3) by two folds.

Cite this Research Publication : S. M. Kadam, Nayak, S. K., and Banerji, A., “Dramatic Influence of Nitrogen Heterocycles on the Activity of Low-Valent Titanium Reagent: An Improved One-Pot Synthesis of Phenanthrenes”, Synthetic communications, vol. 25, pp. 135–142, 1995.

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