Publication Type:

Journal Article

Source:

Journal of Molecular Structure, Volume 885, Number 1-3, p.36-44 (2008)

URL:

http://www.scopus.com/inward/record.url?eid=2-s2.0-46949101639&partnerID=40&md5=7e9290fab7cb82c238ecd4241d14bb32

Keywords:

(I, (PL) properties, Amines, crystal structure, Diaminopropane (DAP), Ethylene diamine (EDA), Fumarate, Fumarates, J) conditions, Nickel, Nickel (II), Nickel alloys, Nickel compounds, Thermodynamic properties

Abstract:

{Lewis-base mediated fragmentation of polymeric nickel(II) fumarate and oxalate are attempted using chelating σ-donor diamines like ethylenediamine (en) and 1,3-diaminopropane (dap) in various conditions which yielded [Ni(en)3](fum)·3H2O (1), [Ni(en)3](ox) (2), [Ni(dap)2(fum)] (3) and [Ni(dap)(ox)]·2H2O (4). While 1 and 2 are molecular products each containing octahedral [Ni(en)3]2+ moieties and the anionic dicarboxylate species, 3 and 4 are dap-incorporated polymeric products. The fumarate derivative 1 containing [Ni(en)3]2+ moieties crystallizes in the monoclinic space group C2/c with a = 17.899(4) Å

Notes:

cited By 7

Cite this Research Publication

Prof. M. Padmanabhan, Joseph, J. C., Huang, X., and Li, J., “Diamine incorporated compounds derived from polymeric nickel(II) fumarates and oxalates: Crystal structure, spectral and thermal properties of [Ni(en)3](O2Csingle bondCHdouble bond, longCHsingle bondCO2)·3H2O and [Ni(en)3](O2Csingle bondCO2)”, Journal of Molecular Structure, vol. 885, pp. 36-44, 2008.

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