Publication Type:

Journal Article

Source:

Inorganic Chemistry, Volume 51, Number 10, p.5605-5616 (2012)

URL:

http://dx.doi.org/10.1021/ic202510d

Abstract:

{ A multicomponent synthetic strategy involving copper(II) ions, tert-butylphosphonic acid (t-BuPO3H2) and 3-substituted pyrazole ligands has been adopted for the synthesis of soluble molecular copper(II) phosphonates. The use of six different 3-substituted pyrazoles, 3-R-PzH [R = H, Me, CF3, Ph, 2-pyridyl (2-Py), and 2-methoxyphenyl (2-MeO-C6H4)] as ancillary ligands afforded nine different decanuclear cages, [Cu5(μ3-OH)2(O3P-t-Bu)3(3-R-Pz)2(X)2]2·(Y) where R = H

Cite this Research Publication

V. Chandrasekhar, Nagarajan, L., Hossain, S., Dr. Gopal K., Ghosh, S., and Verma, S., “Multicomponent Assembly of Anionic and Neutral Decanuclear Copper(II) Phosphonate Cages”, Inorganic Chemistry, vol. 51, pp. 5605-5616, 2012.

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