Publication Type:

Journal Article

Source:

Journal of radioanalytical and nuclear chemistry, Letters, Akadémiai Kiadó, co-published with Springer Science+ Business Media BV, Formerly Kluwer Academic Publishers BV, Volume 175, Number 6, p.415–426 (1993)

Abstract:

The IR spectra of the solvent extracted and extraction chromatographically adsorbed complexes of HNO3, Nd(III), Th(IV) and U(VI) with bifunctional extractants dihexyl N,N-diethylcarbamoylmethylophosphonate (CMP) and octyl (phenyl)-N,N-diisobutylcarbamoyl-methylphosphine oxide (CMPO) have been recorded. The shifts in the P=0 and C=0 streching frequencies have been interpreted. The nitrate ions bound with metal ions were found to be bidentate. The nature of binding of the extractant to the metal ions in the solvent extracted and extraction chromatographically adsorbed complexes were found to be similar.

Cite this Research Publication

J. Mathur, Murali, M., Nagar, M., Natarajan, P., Badheka, L., and Banerji, A., “Solvent extracted and extraction chromatographically adsorbed complexes of bifunctional extractants with f-elements”, Journal of radioanalytical and nuclear chemistry, Letters, vol. 175, pp. 415–426, 1993.

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