Publication Type:

Journal Article

Source:

Journal of Coordination Chemistry, Volume 63, Number 18, p.3301-3312 (2010)

URL:

http://dx.doi.org/10.1080/00958972.2010.511201

Abstract:

Binuclear transition metal complexes of bicompartmental SNONS donors were synthesized and characterized by various physico-chemical techniques. Two different precursors with chloromethyl/formyl functionality at the 2 and 6 positions of phenolate ring are used to construct the ligands. The quinoxaline scaffolds provide SN donors incorporated at the 2 and 6 positions. Copper and zinc complexes are square pyramidal, whereas nickel and cobalt complexes are octahedral. The influence of two metal centers in terms of cooperative effect on the electronic, magnetic, electrochemical, and structural properties was investigated.

Cite this Research Publication

Dr. Naveen V. Kulkarni, Gurunath S. Kurdekar, Srinivasa Budagumpi, and Vidyanand K. Revankar, “Spectroscopy, structure, and electrochemistry of transition metal complexes having [M2N2OS2] coordination sphere”, Journal of Coordination Chemistry, vol. 63, pp. 3301-3312, 2010.