Publication Type:

Journal Article

Source:

Zeitschrift für anorganische und allgemeine Chemie, WILEY-VCH Verlag, Volume 638, Number 11, p.1716–1722 (2012)

URL:

http://dx.doi.org/10.1002/zaac.201200039

Keywords:

Cationic polymers, Dimethyltin, hydrolysis, Organotin cations

Abstract:

N,N′-dioxide ligands such as 2, 2′-bipyridine-N,N-dioxide (BPDO-I) and 4, 4′-bipyridine-N,N-dioxide (BPDO-II) were used to trap the hydrated dimethyltin cations under controlled hydrolysis. The use of the chelating ligand BPDO-I leads to the isolation of the discrete monocation [Me2Sn(BPDO-I)(OH2)(NO3)]+[NO3]– (2), whereas the linear ligand BPDO-II directs the construction of cationic polymers, [{Me2Sn(OH2)2(μ-BPDO-II)}2+{NO3–}2·2H2O]n (3·2H2O) and [{Me2Sn(μ-OH)(BPDO-II)}22+{NO3–}2·H2O]n (4·H2O) under different reaction conditions.

Cite this Research Publication

V. Chandrasekhar, Singh, P., Dr. Gopal K., and Steiner, A., “Trapping Dimethyltin Cations by Bipyridine-N,N′-Dioxide Ligands”, Zeitschrift für anorganische und allgemeine Chemie, vol. 638, pp. 1716–1722, 2012.

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