Unit 1

Introduction
Introduction to nanotechnology, comparison of bulk and nanomaterials – change in band gap and large surface to volume ratio, classification of nanostructured materials. Synthesis of nanomaterials – classification of fabrication methods – top down and bottom up methods.

Concept of quantum confinement and phonon confinement
Basic concepts – excitons, effective mass, free electron theory and its features, band structure of solids. Bulk to nano transition – density of states, potential well – quantum confinement effect – weak and strong confinement regime. Electron confinement in infinitely deep square well, confinement in two and three dimension. Blue shift of band gap – effective mass approximation. Vibrational properties of solids – phonon confinement effect and presence of surface modes.

Unit 2

Tools for characterization:
Structural – X-ray diffraction, transmission electron microscope, scanning tunneling microscope, atomic force microscope. Optical – UV – visible absorption and photoluminescence techniques, Raman spectroscopy.

Nanoscale materials – properties and applications:
Carbon nanostructures – structure, electrical, vibration and mechanical properties. Applications of carbon nanotubes

Unit 3

1. Robert W. Kelsall, Ian W. Hamley and Mark Geoghegan, Nanoscale Science and Technology, John Wiley and Sons Ltd 2004.
2. W. R. Fahrner (Ed.), Nanotechnology and Nanoelectronics, Springer 2006