Syllabus
Unit 1
Basics of Nanomaterials
Introduction to nanomaterials, Comparison of bulk and nanomaterials: Change in band gap, Novel properties of nanomaterial. Classification of nanostructured materials, Synthesis of nanomaterials: Classification and fabrication methods – Top down and bottom-up methods.
Unit 2
Concept of Quantum Confinement and Phonon Confinement
Basic concepts – Excitons, Effective mass, Free electron theory and its features, Band structure of solids. Bulk to nano transition – Density of states, Quantum confinement effect – weak and strong confinement regime. Electron confinement in infinitely deep square well, Confinement in two and three dimension. Blue shift of band gap, Effective mass approximation. Vibrational properties of Solids – Phonon Confinement effect and presence of surface modes.
Unit 3
Tools for Characterization
Structural: X-ray Diffraction, Surface Analysis: Transmission Electron Microscope, Scanning Tunneling Microscope, Atomic Force Microscope, Optical studies: UV – Visible absorption, Photoluminescence, Raman spectroscopy.
Unit 4
Nanostructured Materials
Carbon nanotubes: Structure, electrical, vibration and mechanical properties, Applications of carbon nanotubes – Field emission and shielding, Computers, Fuel cells, Chemical sensors, Catalysis, Mechanical reinforcement. Quantum dots and Magnetic nanomaterials – Applications.
Unit 5
Nanoelectronics and Nanodevices
Impact of nanotechnology on conventional electronics, Nanoelectromechanical systems (NEMSs): Fabrication (Lithography) and applications, Nanodevices: Resonant tunneling diode, Quantum cascade lasers, Single electron transistors: Operating principles and applications.