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Catalytic effects of poly(methyl methacrylate) supported β-diketone linked palladium complexes in olefin oxidation

Publication Type : Journal Article

Publisher : Springer

Source : Journal of Chemical Sciences, 2002

Url :

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2002

Abstract : Poly(methyl methacrylate)-supportedβ-diketone-linked palladium complexes on refluxing with olefins at 70°C in methanol-water medium for 10 h afforded carbonyl compounds. The course of the reaction was found to be influenced by the degree of cross-linking of the polymer matrix and the structural environment of the ligand. The reaction is assumed to proceed through a hydroxy palladation intermediate. A suitable mechanism is also suggested.

Cite this Research Publication : Vipin A. Nair, M. M. Suni and K. Sreekumar, "Catalytic effects of poly(methyl methacrylate)-supportedβ-diketone-linked palladium complexes in olefin oxidation", Journal of Chemical Sciences, 2002, 114, 481-486

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