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Dielectric behavior of CaCu3Ti4O12 electro-ceramic doped with La, Mn and Ni synthesized by modified citrate-gel route

Publication Type : Journal Article

Thematic Areas : Nanosciences and Molecular Medicine

Publisher : Journal of Advanced Ceramics

Source : Journal of Advanced Ceramics, Tsinghua Press, Volume 2, Number 2, p.119–127 (2013)

Url : is external)

Campus : Kochi

School : Center for Nanosciences

Center : Nanosciences

Department : Nanosciences

Verified : Yes

Year : 2013

Abstract : The effect of La3+, Mn2+ and Ni2+ doped calcium copper titanate, CaCu3Ti4O12 (CCTO), at higher concentrations (CR1 and CR2 with 5 mol% and 10 mol%, respectively), has been examined by semi-wet route at relatively lower temperature. This semi-wet route employs citrate-nitrate gel chemical method using TiO2 solid powders. X-ray diffraction (XRD) analysis confirms the formation of single phase in the doped samples sintered at 900 °C for 8 h. Scanning electron micrographs (SEM) show that the average grain size for CR2 is larger than that of CR1 composition. The energy dispersive X-ray spectroscopy (EDX) is used to study the percentage compositions of different ions present in both ceramics. Dielectric constant (ɛ r) and dielectric loss (tan$δ$) values of CR1 are comparatively higher than those of CR2 ceramic at all measured frequencies and temperatures. The nature of temperature-dependent relaxation behavior of the ceramics is also studied by impedance, modulus spectroscopic analysis and confirms Maxwell-Wagner relaxation.

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