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Homolytic displacements at carbon in organocobaloximes: Reactions of organocobaloximes with free radical precursor with two radical centres

Publication Type : Journal Article

Thematic Areas : Advanced Materials and Green Technologies

Publisher : Indian Journal of Chemistry

Source : Indian Journal of Chemistry Section a-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry, Volume 40, p.986-988 (2001)

Campus : Coimbatore

School : School of Engineering

Center : Center for Excellence in Advanced Materials and Green Technologies

Department : Sciences, Chemistry, Civil

Year : 2001

Abstract : The reactions Of MeC6H4-SO2-SPh with organocobaloximes, RCo(dingH)(2)Py, (R = alkyl, benzyl, butenyl and allyl) under visible light photolysis show that the alkyl, butenyl and benzyl cobaloximes form the corresponding sulphides whereas the allyl cobaloximes form the organic sulphones.

Cite this Research Publication : B. Gupta, Oberoi, M., Mandal, D., Tiwari, U., Dr. Yamuna R., Vijaikanth, V., and Singh, V., “Homolytic displacements at carbon in organocobaloximes: Reactions of organocobaloximes with free radical precursor with two radical centres”, Indian Journal of Chemistry Section a-Inorganic Bio-Inorganic Physical Theoretical & Analytical Chemistry, vol. 40, pp. 986-988, 2001.

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