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Nanocrystalline tin disulfide coating of reduced graphene oxide produced by the peroxostannate deposition route for sodium ion battery anodes

Publication Type : Journal Article

Publisher : J. Mater. Chem. A

Source : Journal of Materials Chemistry A Volume 2 Issue 22 Pages 8431-8437, 2014

Url : https://pubs.rsc.org/en/content/articlelanding/2014/ta/c3ta15248k/unauth

Campus : Coimbatore

School : School of Physical Sciences

Center : Center for Industrial Research and Innovation (ACIRI)

Year : 2014

Abstract : A highly stable sodium ion battery anode was prepared by deposition of hydroperoxostannate on graphene oxide from hydrogen-peroxide-rich solution followed by sulfidization and 300 [degree]C heat treatment. The material was characterized by electron microscopy{,} powder X-ray diffraction and X-ray photoelectron spectroscopy which showed that the active material is mostly rhombohedral SnS2 whose (001) planes were preferentially oriented in parallel to the graphene oxide sheets. The material exhibited gt;610 mA h g-1 charge capacity at 50 mA g-1 (with gt;99.6% charging efficiency) between 0 and 2 V vs. Na/Na+ electrode{,} high cycling stability for over 150 cycles and very good rate performance{,} gt;320 mA h g-1 at 2000 mA g-1.

Cite this Research Publication : Petr V Prikhodchenko, YW Denis, Sudip K Batabyal, Vladimir Uvarov, Jenny Gun, Sergey Sladkevich, Alexey A Mikhaylov, Alexander G Medvedev, Ovadia Lev, "Nanocrystalline tin disulfide coating of reduced graphene oxide produced by the peroxostannate deposition route for sodium ion battery anodes", Journal of Materials Chemistry A Volume 2 Issue 22 Pages 8431-8437, 2014

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