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Polystyrene supported β-diketone linked palladium complexes for olefin oxidation

Publication Type : Journal Article

Publisher : Taylor & Francis

Source : Designed Monomers and Polymers, 2003

Url :

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2003

Abstract : Polystyrene-supported β-diketone-linked palladium complexes on refluxing with olefins at 70°C in a methanol-water medium for 10 h afforded carbonyl compounds. The course of the reaction was influenced by the degree of cross-linking of the polymer matrix, the distance between the polymer matrix and the metal complex, and the structural environment of the ligand. The reaction is assumed to proceed through a hydroxy-palladation intermediate. A suitable mechanism is also suggested.

Cite this Research Publication : Vipin A. Nair, M. M. Suni and K. Sreekumar, "Catalytic studies on polymer supported metal complexes", Designed Monomers and Polymers 2003, 6, 81-89

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