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Publication Type : Journal Article
Publisher : ABC
Source : ABC 2013, 03 (06), 521–524. https://doi.org/10.4236/abc.2013.36058.
Keywords : Alkyl Hydrazine; Radical Alkylation; Caffeine; Homolytic Aromatic Substitution; Pentaamminecobalt(III)
Campus : Amritapuri
School : School of Biotechnology
Department : Chemistry
Year : 2013
Abstract : Alkyl xanthines underwent selective homolytic aro- matic substitution at C-8 position with alkyl groups of pentaamminecobalt(III) complex. In this process of synthesis, we used monoalkyl hydrazines as the ra- dical source in aqueous ammonia solution. Evidence supporting coordination of the alkyl hydrazine to pentaamminecobalt(III) complex by radical trapping was in good agreement with literature. The products were characterized using GC-MS and 1H, 14N and 59Co NMR spectroscopy
Cite this Research Publication : Suravajhala, R. Synthesis of C-8 Alkyl Xanthines by Pentaamminecobalt(III) Complex. ABC 2013, 03 (06), 521–524. https://doi.org/10.4236/abc.2013.36058.