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Microstructural transition from ZrO₂ to Zr–Al intermetallics and property evolution in AA5051 composites

Publication Type : Journal Article

Publisher : Elsevier BV

Source : Journal of Materials Research and Technology

Url : https://doi.org/10.1016/j.jmrt.2025.01.201

Keywords : Al5051 alloy, Squeeze casting, Grain refinement, Mechanical properties, Corrosion, Wear rate

Campus : Chennai

School : School of Engineering

Department : Mechanical Engineering

Year : 2025

Abstract : AA5051 is lightweight and has excellent corrosion resistance, but it loses strength at higher temperatures as magnesium atoms diffuse more readily within the aluminium matrix, reducing the uniformity of the solid solution and weakening the alloy's strengthening mechanism. Incorporating ZrO2 addresses these challenges by refining the grain structure, generating thermally stable secondary phases, and minimising diffusion processes which influence mechanical properties at elevated temperatures. In the current scenario, ZrO2-reinforced AA5051 alloy composites were synthesised by the squeeze casting process, and its microstructure and mechanical characteristics were analysed for high-performance components. Microstructural observations show that ZrO2 particles distribute evenly throughout the alloy matrix without yielding residual pores, and they thrive as nucleation sites during solidification to inhibit recrystallisation. The tensile (24.12 ± 0.01%), compressive (22.55 ± 0.02%), flexural (21.42 ± 0.01%), and impact (32.39 ± 0.01%) characteristics are enhanced by good interfacial bonding, better stress distribution and increases in dislocation density between the intermixture. Al2O3 forms on the alloy surface with the aid of ZrO2, and it functions as a protective barrier against corrosion and further oxidation. The inclusion of hard ZrO₂ particles minimised wear loss percentage in synthesised composites by reducing direct contact between the matrix and wear surface, resulting in less adhesive wear.

Cite this Research Publication : G. Anbuchezhiyan, G. Ananth, Vignesh M, K. Logesh, Nabisab Mujawar Mubarak, Elango Natarajan, Microstructural transition from ZrO₂ to Zr–Al intermetallics and property evolution in AA5051 composites, Journal of Materials Research and Technology, Elsevier BV, 2025, https://doi.org/10.1016/j.jmrt.2025.01.201

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