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Multifunctional role of tannic acid in improving the mechanical, thermal and antimicrobial properties of natural rubber-molybdenum disulfide nanocomposites

Publication Type : Journal Article

Publisher : Elsevier

Source : A.S sethulekshmi,Kuruvilla Joseph, Abi Santhosh Aprem, Suja Bhargavan Sisupal, Vidhu S Nair, S Sidharth

Url : https://www.sciencedirect.com/science/article/pii/S0141813022026137

Campus : Amritapuri

School : School of Physical Sciences

Department : Chemistry

Year : 2023

Abstract : Natural rubber is the only biosynthesized rubber and the most prominent of all the elastomers. Insertion of nanofillers into natural rubber matrix has received much research interest because of the enhanced mechanical, thermal, electrical, antibacterial, etc. properties of the final natural rubber nanocomposite. Molybdenum disulfide (MoS2), an important member in transition metal dichalcogenides (TMD) is having excellent optical, thermal, mechanical, electronic and antibacterial properties. The inherent properties of this novel filler was exploited through the preparation of natural rubber-MoS2 nanocomposites via latex dipping method in which tannic acid (TA), naturally occurring macromolecule was used as an exfoliating agent for MoS2. MoS2:TA dispersions were prepared in 1:2, 1:4 and 1:6 ratios by mechanical stirring followed by sonication method for analyzing the optimum amount of exfoliating agent for the preparation of NR-MoS2 nanocomposite. MoS2:TA in 1:4 ratio was found to be the optimum loading for the NR nanocomposite preparation with improved mechanical, thermal and antibacterial properties. The enhanced properties of the NR composites could be attributed to the synergistic effect of both MoS2 and TA. The current study shows the role of TA in tuning the properties of NR/MoS2 nanocomposites that enable their potential utilization in various biomedical applications.

Cite this Research Publication : A.S sethulekshmi , Saritha Appukuttan , Kuruvilla Joseph, Abi Santhosh Aprem , Suja Bhargavan Sisupal , Vidhu S Nair, S Sidharth, Multifunctional role of tannic acid in improving the mechanical, thermal and antimicrobial properties of natural rubber-molybdenum disulfide nanocomposites, International Journal of biological macromolecules, Volume 225, 15 January 2023, pages 351-360.

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