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Reduction of aldehydes and ketones by NaBH4 in presence of 1-alkyl-1, 2, 4-triazolium salts

Publication Type : Journal Article

Publisher : Elsevier

Source : Materials Today: Proceedings Volume 33 Pages 2381-2384

Url : https://www.sciencedirect.com/science/article/abs/pii/S2214785320340505

Campus : Coimbatore

School : School of Physical Sciences

Department : Department of Sciences

Year : 2020

Abstract : We have synthesized two ionic liquids namely 1-hexyl-1,2,4-triazolium methanesulfonate and 1-hexyl-1,2,4-triazolium trifluoroacetate. We have carried out the reduction of various aldehydes and ketones by NaBH4 in the presence of the synthesized ionic liquids. Cinnamaldehyde and acetophenone are used for the optimization of the reaction condition. Reduction of different aldehydes and ketones were carried out and a good yield of product is obtained where the ionic liquid with anion methanesulfonate is used. In the case of ketones, ionic liquid 1-hexyl-1,2,4-triazolium trifluoroactetate gives a good yield.

Cite this Research Publication : Krishnan M Gayathri, Sreedevi Paramparambath, Anjitha Satheesh, Susithra Selvam, Elango Kandasamy, "Reduction of aldehydes and ketones by NaBH4 in presence of 1-alkyl-1, 2, 4-triazolium salts", Materials Today: Proceedings Volume 33 Pages 2381-2384 2020

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