Back close

Trapping Dimethyltin Cations by Bipyridine-N,N′-Dioxide Ligands

Publication Type : Journal Article

Publisher : WILEY-VCH Verlag

Source : Zeitschrift für anorganische und allgemeine Chemie, WILEY-VCH Verlag, Volume 638, Number 11, p.1716–1722 (2012)

Url :

Keywords : Cationic polymers, Dimethyltin, hydrolysis, Organotin cations

Campus : Amritapuri

School : School of Arts and Sciences

Department : Chemistry

Year : 2012

Abstract : N,N′-dioxide ligands such as 2, 2′-bipyridine-N,N-dioxide (BPDO-I) and 4, 4′-bipyridine-N,N-dioxide (BPDO-II) were used to trap the hydrated dimethyltin cations under controlled hydrolysis. The use of the chelating ligand BPDO-I leads to the isolation of the discrete monocation [Me2Sn(BPDO-I)(OH2)(NO3)]+[NO3]– (2), whereas the linear ligand BPDO-II directs the construction of cationic polymers, [{Me2Sn(OH2)2(μ-BPDO-II)}2+{NO3–}2·2H2O]n (3·2H2O) and [{Me2Sn(μ-OH)(BPDO-II)}22+{NO3–}2·H2O]n (4·H2O) under different reaction conditions.

Cite this Research Publication : Vadapalli Chandrasekhar, Puja Singh, Dr. Gopal K., and Alexander Steiner, “Trapping Dimethyltin Cations by Bipyridine-N,N′-Dioxide Ligands”, Zeitschrift für anorganische und allgemeine Chemie, vol. 638, pp. 1716–1722, 2012.

Admissions Apply Now