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Publication Type : Journal Article
Publisher : Alpha Science Int'l Ltd.
Source : Ion Conducting Materials: Theory and Applications Pages 9, 2001
Campus : Coimbatore
School : School of Physical Sciences
Year : 2001
Abstract : The ionic conductivity (o) of LiCl-NaCl binary system has been studied as function of composition and temperature. The electrical conductivity in the intrinsic region as function of composition has been correlated with the phase-diagram. A maximum enhancement in σ by a factor of~ 4 x 103 with respect to pure NaCl is obtained at 560 C for 70 m/o LiCl where melting point is minimum. The conductivity enhancement in the intrinsic region of different compositions, can be explained in terms of lattice loosening model in accordance with the phase diagram.
Cite this Research Publication : BTS Ramanujam, K Shahi, "WRONG SIZE EFFECT IN NaCl-LiCI MIXED CRYSTALS", Ion Conducting Materials: Theory and Applications Pages 9, 2001