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Anti selective glycolate aldol reactions of (S)-4-isopropyl-1-[(R)-1-phenylethyl]imidazolidin-2-one: application towards the asymmetric synthesis of 8-4ꞌ-oxyneolignans

Publication Type : Journal Article

Publisher : Royal Society of Chemistry

Source : RSC Advances, 2016

Url : https://pubs.rsc.org/en/content/articlehtml/2016/ra/c6ra22026f?casa_token=E5AUyMROV0IAAAAA:xLT4sbQB0vzTzaxpXt6D8LORzfec-TpJJ2wteZGFhjV41vf6RJNXgVo76WYnymcpMlFzuFAYwHCHFhk

Campus : Amritapuri

School : School of Biotechnology

Verified : No

Year : 2016

Abstract : The anti selective glycolate aldol reactions of (S)-4-isopropyl-1-[(R)-1-phenylethyl]imidazolidin-2-one auxiliary have been standardized with high yields and excellent diastereoselectivities on various substituted aryl, allyl and alkyl aldehydes. The optimized reaction conditions were employed for the stereoselective synthesis of oxyneolignans.

Cite this Research Publication : Mukesh Gangar, Avinash Ittuveetil, Sandeep Goyal, Anang Pal, Harikrishnan M. and Vipin A.Nair, "Anti selective glycolate aldol reactions of (S)-4-isopropyl-1-[(R)-1-phenylethyl]imidazolidin-2-one: application towards the asymmetric synthesis of 8-4ꞌ-oxyneolignans", RSC Advances 2016, 6, 102116-102126

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