Publication Type : Journal Article
Publisher : Journal of Coordination Chemistry
Source : Journal of Coordination Chemistry, Volume 63, Number 12, p.2172-2180 (2010)
Url : http://dx.doi.org/10.1080/00958972.2010.497553
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2010
Abstract : A series of Co(II), Ni(II), Cu(II), and Zn(II) complexes of bi- and tridentate hydrazones were prepared. Ligands L1 and L2 were synthesized by the condensation of 2-mercapto-3-hydrazinoquinoxaline with 2-hydroxy-3-formylquinoline and 3-acetylcoumarin, respectively. The compounds were characterized by various spectro-analytical techniques and magnetic moment studies. The complexes are found to be monomeric and non-electrolytes. In these complexes, [CuL1Cl2] has square pyramidal geometry and others have octahedral. The copper complexes are electrochemically active in the applied potential range.
Cite this Research Publication : Gurunath S. Kurdekar, Dr. Naveen V. Kulkarni, Srinivasa Budagumpi, M. P. Sathisha, Nagaraj H. Bevinhalli, and Vidyanand K. Revankar, “Construction of mononuclear transition metal(II) complexes with bi- and tridentate, neutral hydrazone ligands with a quinoxaline hub”, Journal of Coordination Chemistry, vol. 63, pp. 2172-2180, 2010