Publication Type : Presentation
Publisher : First Annual Symposium of center for energy and environment (Poster), University of Rochester, Rochester, NY, United States.
Source : First Annual Symposium of center for energy and environment (Poster), University of Rochester, Rochester, NY, United States (2016)
Campus : Amritapuri
School : School of Arts and Sciences
Department : Chemistry
Year : 2016
Abstract : The cationic zinc adduct {[HB(3,5-(CF3)2Pz)3]Zn(NCMe)2}ClO4 catalyzes the functionalization of tertiary, secondary, and primary C–H bonds of alkanes via carbene insertion. Ethyl diazoacetate serves as the :CHCO2Et carbene precursor. The counteranion, supporting ligand, and coordinating solvents affect the catalytic activity. An in situ generated {[HB(3,5-(CF3)2Pz)3]Zn}+ species containing a bulkier {B[3,5-(CF3)2C6H3]4}− anion gives the best results among the zinc catalysts used.
Cite this Research Publication : Dr. Naveen V. Kulkarni, “Zinc Mediated Carbene Insertion into C-H and C-Cl bonds”, First Annual Symposium of center for energy and environment (Poster). University of Rochester, Rochester, NY, United States, 2016.
