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Extraction chromatographic separation and recovery of plutonium from oxalate supernatant using CMPO

Publication Type : Journal Article

Thematic Areas : Biotech

Publisher : Taylor & Francis

Source : Journal of Nuclear Science and Technology, Taylor & Francis, Volume 30, Number 11, p.1198–1200 (1993)

Campus : Amritapuri

School : School of Biotechnology

Center : Biotechnology, Phytochemistry Labs

Department : biotechnology, Chemistry

Year : 1993

Abstract : The conversion of plutonium nitrate solution to plutonium oxide via oxalate precipitation route leads to a large volume of oxalate supernatant which contains'30 mg/dm'of Pu in'3 mol/dm'HNO, and 0.1 mol/dm'oxalic acid. Plutonium can be recovered from such solutions after the destruction of oxalic acid for which the conventional methods are:(1) Addition of KMn04 and then destroying excess KMnO, by H202.(2) Concentration of the supernatant to high terminal HNO, concentration of 10 mol/dm'at high temperature 1. The first method...

Cite this Research Publication : J. N. Mathur, Murali, M. S., Rizvi, G. H., Iyer, R. H., Michael, K. M., KAPOORT, S. C., Ramanujam, A., Badheka, L. P., and Banerji, A., “Extraction chromatographic separation and recovery of plutonium from oxalate supernatant using CMPO”, Journal of Nuclear Science and Technology, vol. 30, pp. 1198–1200, 1993.

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